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In situ synthesis of tower-like Ag-Sm(OH)3-ZnO photocatalyst with enhanced visible-light-driven photocatalytic activity
Materials Science and Engineering: B ( IF 3.6 ) Pub Date : 2019-11-14 , DOI: 10.1016/j.mseb.2019.114449
Lixiong Yin , Changqing Liu , Jia Wang , Feifei Wang , Simin Chai , Dongdong Zhang , Xingang Kong , Huimin Li , Jianfeng Huang

3D tower-like Ag-Sm(OH)3-ZnO morphologies were successfully synthesized via a facile in situ method by utilizing Sm(OH)3-ZnO as the precursor. The scanning electron microscopy (SEM) images reveal that the 3D tower-like Sm(OH)3-ZnO samples were grown to a 3D tower-shape. Additionally, silver nanoparticles were uniformly dispersed on the surface of Sm(OH)3-ZnO. The photo catalytic performances of the as-prepared Ag-Sm(OH)3-ZnO samples were evaluated towards the removal of Rhodamine B (RhB) upon visible-light irradiation. Compared with 70% degradation efficiency of RhB solution over Sm(OH)3-ZnO under visible-light irradiation for 120 min, the 3D tower-like Ag-Sm(OH)3-ZnO hybrid could reach 98% under the same conditions. This superior performance could be attributed to the surface plasmon resonance (SPR) and Heterojunction effect induced through the addition of Ag.



中文翻译:

具有增强的可见光驱动光催化活性的塔状Ag-Sm(OH)3 -ZnO光催化剂的原位合成

以Sm(OH)3 -ZnO为前驱体,通过简便的原位方法成功合成了3D塔状Ag-Sm(OH)3 -ZnO形态。扫描电子显微镜(SEM)图像显示,将3D塔状Sm(OH)3 -ZnO样品生长为3D塔状。另外,银纳米颗粒均匀地分散在Sm(OH)3 -ZnO的表面上。评估了制备的Ag-Sm(OH)3 -ZnO样品在可见光照射下对若丹明B(RhB)去除的光催化性能。与RhB溶液对Sm(OH)3的70%降解效率相比-ZnO在可见光照射120分钟后,在相同条件下3D塔状Ag-Sm(OH)3 -ZnO杂化物可达到98%。这种优异的性能可以归因于通过加入Ag诱导的表面等离子体共振(SPR)和异质结效应。

更新日期:2019-11-14
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