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Synthesis and Characterization of a Novel Self-colored Fluorescent Polycarbonate Urethane based on the 1,8-Naphthalimide Group
Journal of Macromolecular Science Part B-Physics ( IF 1.4 ) Pub Date : 2019-08-20 , DOI: 10.1080/00222348.2019.1635726
Ehsan Zamani 1 , Hossein Yahyaei 1 , Alireza Khosravi 1 , Mohsen Mohseni 1 , Hanieh Shaki 2
Affiliation  

The synthesis of a novel self-colored polyurethane (PU) is described using 4-amino-N-propanoic acid-1,8-naphthalimide dye. To synthesize the self- colored PU, the dye was added to the PU prepolymer at the chain extension step. PU and self-colored PU were characterized by using Fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy and Fluorometry. The thermal behavior of the PU and self-colored PU were investigated by differential scanning calorimetry (DSC). The spectra indicated that the addition of dye to the polymer chain did not affect the glass transition temperature (Tg = -39 °C). Tensile strengths and Young’s modulus of the samples were assessed using a tensile strength test; they revealed that addition of the dye to the polymer structure enhanced the Young’s modulus and increased the mechanical strength of the PU. X-ray diffraction (XRD) was used for evaluation of the crystal phase of the polymer; it revealed that both components were amorphous.



中文翻译:

基于1,8-萘二甲酰亚胺基的新型自着色荧光聚碳酸酯氨基甲酸酯的合成与表征

使用4-氨基-N-丙酸-1,8-萘二甲酰亚胺染料描述了新型自着色聚氨酯(PU)的合成。为了合成自着色的PU,在扩链步骤将染料加入到PU预聚物中。通过使用傅立叶变换红外光谱(FTIR),紫外可见光谱和荧光法对聚氨酯和自着色聚氨酯进行了表征。通过差示扫描量热法(DSC)研究了PU和自着色PU的热行为。光谱表明,向聚合物链中添加染料不会影响玻璃化转变温度(T g = -39°C)。使用拉伸强度测试评估样品的拉伸强度和杨氏模量。他们发现,将染料添加到聚合物结构中可以提高杨氏模量,并提高聚氨酯的机械强度。X射线衍射(XRD)用于评估聚合物的晶相;结果表明这两种成分都是非晶态的。

更新日期:2019-11-13
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