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Verification of the de Wolff hypothesis concerning the symmetry of β-MnO2
Acta Crystallographica Section A Foundations and Advances Pub Date : 2019-11-04 , DOI: 10.1107/s2053273319013408
Piotr Fabrykiewicz , Radosław Przeniosło , Izabela Sosnowska , François Fauth , Dariusz Oleszak

The symmetry lowering from tetragonal to orthorhombic is demonstrated using high-resolution diffraction and also justified by using the magnetic superspace groups formalism for the rutile-type compound β-MnO2. The (lower) orthorhombic symmetry is observed at temperatures both below and above the Néel temperature. The magnetic ordering of β-MnO2is of spin density type and not screw-type helical. The results support the de Wolff [Acta Cryst.(1959),12, 341–345] hypothesis about the orthorhombic symmetry of β-MnO2.

中文翻译:

关于 β-MnO2 对称性的德沃尔夫假说的验证

使用高分辨率衍射证明了对称性从四方晶系降低到斜方晶系,并且还通过使用金红石型化合物 β-MnO 的磁性超空间群形式主义证明了对称性的合理性2。在低于和高于尼尔温度的温度下都观察到(下)斜方对称性。β-MnO的磁有序性2是自旋密度型而不是螺杆型螺旋。结果支持 de Wolff [阿克塔水晶。(1959),12,341–345]关于β-MnO的斜方对称性的假设2
更新日期:2019-11-04
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