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NAP-XPS study of Eu3+ → Eu2+ and Ce4+ → Ce3+ reduction in Au/Ce0.80Eu0.20O2 catalyst
Catalysis Communications ( IF 3.7 ) Pub Date : 2019-11-05 , DOI: 10.1016/j.catcom.2019.105875
O.S. Bezrkovnyi , M. Vorokhta , M. Małecka , W. Mista , L. Kepinski

Eu3+ → Eu2+ and Ce4+ → Ce3+ reduction in Au/Ce0.80Eu0.20O2 catalyst were systematically studied using in-situ NAP-XPS technique. The reduction of Eu3+ → Eu2+ in the ceria, in a hydrogen atmosphere at temperature ≥ 400 °C, has been demonstrated for the first time. The effect of the reduction of Ce0.80Eu0.20O2 support on the catalytic activity of Au nanoparticles in CO oxidation has been investigated.



中文翻译:

NAP-XPS研究Eu / Ce 0.80 Eu 0.20 O 2催化剂中Eu 3+  →Eu 2+和Ce 4+  →Ce 3+还原

利用原位NAP-XPS技术系统地研究了Au / Ce 0.80 Eu 0.20 O 2催化剂中Eu 3+  →Eu 2+和Ce 4+  →Ce 3+的还原。首次证明了在温度≥400°C的氢气气氛中,二氧化铈中Eu 3+  →Eu 2+的还原。研究了Ce 0.80 Eu 0.20 O 2载体的还原对Au纳米颗粒在CO氧化中催化活性的影响。

更新日期:2019-11-06
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