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Selective synthesis of pyrimidines from cinnamyl alcohols and amidines using the heterogeneous OMS-2 catalyst
Catalysis Communications ( IF 3.7 ) Pub Date : 2019-10-31 , DOI: 10.1016/j.catcom.2019.105846
Jian Shen , Xu Meng

Herein, an efficient aerobic oxidative synthesis of pyrimidines was carried out using cinnamyl alcohols and amidines catalyzed by manganese oxide octahedral molecular sieve (OMS-2). The heterogeneous catalytic method features base-/additive-free conditions, wide substrate scope, use of O2 as a green oxidant, and simple operation. Moreover, the OMS-2 catalyst prepared by the conventional reflux method demonstrates catalytic selectivity, activity, and excellent recyclability.



中文翻译:

使用多相OMS-2催化剂从肉桂醇和am选择性合成嘧啶

在此,使用肉桂醇和由氧化锰八面体分子筛(OMS-2)催化的am进行了嘧啶的有效好氧氧化合成。该多相催化方法具有无碱/无添加剂的条件,较宽的底物范围,使用O 2作为绿色氧化剂以及操作简单的特点。而且,通过常规回流方法制备的OMS-2催化剂表现出催化选择性,活性和优异的可循环性。

更新日期:2019-11-01
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