Allyl alcohol, a toxic compound with mutagenic nature, is known to be very harmful for humans. Due to its demand as industrial chemical with hazardous characteristics, its recognition and capture is of high topical interest. Metal–organic frameworks (MOFs) have emerged as front-runners for the recognition of various environmentally-toxic molecules or biologically-active reactive species, owing to their design flexibility and ability to anchor guest-specific sites. In the present investigation, the targeted selective detection of allyl alcohol in two rationally constructed MOFs is reported. This systematic study emphasizes that the interaction of allyl alcohol with coordinated functional sites has a pronounced effect on its screening from other small alcohols via a luminescence pathway. The experimental findings were further supported the theoretical calculations.

中文翻译：

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孔功能化的金属有机框架对有毒烯丙醇的特异性识别

烯丙醇是一种具有诱变性的有毒化合物，已知对人体非常有害。由于其作为具有危险特性的工业化学品的需求，其识别和捕获备受关注。金属有机框架（MOFs）由于其设计灵活性和锚定特定客体的能力而成为公认的各种环境毒性分子或具有生物活性的反应物种的领先者。在本研究中，报道了在两个合理构建的MOF中针对性选择性检测烯丙醇的报道。这项系统的研究强调，烯丙醇与协调的功能性位点之间的相互作用对通过其他小醇进行的筛选具有显着影响。发光途径。实验结果进一步支持了理论计算。