The production of polybenzoxazines from natural renewable materials has attracted interest because of the environmental impacts caused by conventional petroleum-based materials. This is a comprehensive review of benzoxazine resins using natural renewable raw materials. Substances, extracted from the nature, or converted from agro-waste or byproducts of the environmental industry, are utilized to synthesize benzoxazine monomers, and their polymerization behavior and the properties of polymers have been discussed. Diversity of structural features and unique functions make natural renewable materials potential candidates for high-performance benzoxazine resins. Abundance, low price, multi-approach available bio-based waste are the driving force of future applications. Papers on the manufacturing of polybenzoxazine blends and composites with renewable fillers and their applications have also been reviewed.

由于常规石油基材料对环境的影响，由天然可再生材料生产聚苯并恶嗪引起了人们的兴趣。这是对使用天然可再生原料的苯并恶嗪树脂的全面综述。从自然界中提取的物质，或从环境工业的农业废物或副产品中转化的物质被用于合成苯并恶嗪单体，并且已经讨论了它们的聚合行为和聚合物的性能。结构特征和独特功能的多样性使天然可再生材料成为高性能苯并恶嗪树脂的潜在候选者。数量丰富，价格低廉，可采用多种方法处理的生物废料是未来应用的驱动力。