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Synthesis of Well‐Defined Poly(norbornene) Containing Carbon Nanodots by Controlled ROMP
Journal of Polymer Science Part A: Polymer Chemistry ( IF 2.869 ) Pub Date : 2019-10-10 , DOI: 10.1002/pola.29506
Ki‐Taek Bang 1 , Tae‐Lim Choi 1
Affiliation  

We reported the synthesis of well‐defined poly(norbornene) having hexa‐peri‐hexabenzocoronene (HBC) moiety by ROMP. After optimization, the 3rd generation Grubbs catalyst enabled precise control of the molecular weight of the polymer with a narrow dispersity. This controlled polymerization led us to prepare the preparation of the block copolymer containing HBC for the first time.
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中文翻译:

受控ROMP法合成定义良好的含碳纳米点的聚降冰片烯

我们报道具有六该明确定义的聚(降冰片烯)的合成通过ROMP -hexabenzocoronene(HBC)部分。经过优化后,第三代Grubbs催化剂可以精确控制聚合物的分子量,并具有较窄的分散度。这种受控的聚合反应使我们首次制备了含HBC的嵌段共聚物。
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更新日期:2019-10-10
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