Supra-amphiphiles provide a brand-new powerful strategy for the construction of functional materials and have shown fascinating prospects in a variety of fields. When merged with chirality science, the concept of chiral supra-amphiphiles arises, which is an important subclass of supra-amphiphiles. In this review, we have provided a general introduction to the concept and design principle of chiral supra-amphiphiles as well as their self-assemblies. We have also highlighted some progress of chiral supra-amphiphiles in several application fields, such as chiroptical switches, chiral recognition, chiral catalysis and chiral luminescent soft materials. Although some elegant reviews have comprehensively looked back at the development and achievement of supra-amphiphiles, their research progress in chirality science has not been well summarized. We hope this review will provide useful guidance and understanding of self-assembly of chiral supra-amphiphiles, which we believe will benefit scientists in both colloidal chemistry and chirality science.

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手性超两亲分子的自组装

超两亲性为功能材料的构建提供了一种全新的有力策略，并且在各个领域都显示出令人着迷的前景。当与手性科学融合时，便出现了手性超两亲概念，这是超两亲的重要子类。在这篇综述中，我们对手性超两亲药物的概念和设计原理以及它们的自组装进行了一般性介绍。我们还强调了手性超两亲药物在一些应用领域中的一些进展，例如手性开关，手性识别，手性催化和手性发光软材料。尽管一些优雅的评论全面回顾了超两亲分子的发展和成就，但它们在手性科学方面的研究进展尚未得到很好的总结。