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Platinum-mediated B-H methoxylation of bis(pyrazolyl)borate.
Faraday Discussions ( IF 3.797 ) Pub Date : 2019-12-02 , DOI: 10.1039/c9fd00052f
Shrinwantu Pal,Brian O Patrick,Jennifer A Love

A new bis(pyrazolyl)dihydridoborato diphenylplatinum(ii) complex was found to react with methanol to form H2 and a new diphenylplatinum(ii) complex supported by bis(pyrazolyl)dimethoxyborate. When performed in CD3OD, in addition to the expected installation of OCD3 fragments on the B-center and concomitant formation of H-D, deuteration of PtII(C6H5)2 fragments was observed. In contrast, dissolution of the bis(pyrazolyl)dimethoxyborato diphenylplatinum(ii) complex in CD3OD led to neither deuteration of PtII(C6H5)2 fragments nor substitution of B-bound methoxy fragments. A mechanism discussing the role of the PtII-center is presented.
更新日期:2019-12-04

 

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