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Large linear magnetoelectric effect and field-induced ferromagnetism and ferroelectricity in DyCrO 4
NPG Asia Materials ( IF 9.7 ) Pub Date : 2019-09-27 , DOI: 10.1038/s41427-019-0151-9
Xudong Shen , Long Zhou , Yisheng Chai , Yan Wu , Zhehong Liu , Yunyu Yin , Huibo Cao , Clarina Dela Cruz , Young Sun , Changqing Jin , Angel Muñoz , José Antonio Alonso , Youwen Long

All the magnetoelectric properties of scheelite-type DyCrO4 are characterized by temperature- and field-dependent magnetization, specific heat, permittivity, electric polarization, and neutron diffraction measurements. Upon application of a magnetic field within ±3 T, the nonpolar collinear antiferromagnetic structure leads to a large linear magnetoelectric effect with a considerable coupling coefficient. An applied electric field can induce the converse linear magnetoelectric effect, realizing magnetic field control of ferroelectricity and electric field control of magnetism. Furthermore, a higher magnetic field (>3 T) can cause a metamagnetic transition from the initially collinear antiferromagnetic structure to a canted structure, generating a large ferromagnetic magnetization up to 7.0 μB f.u.−1. Moreover, the new spin structure can break the space inversion symmetry, yielding ferroelectric polarization, which leads to coupling of ferromagnetism and ferroelectricity with a large ferromagnetic component.



中文翻译:

DyCrO 4中的大线性磁电效应和场致铁磁和铁电

白钨矿型DyCrO 4的所有磁电特性都取决于与温度和场相关的磁化强度,比热,介电常数,电极化和中子衍射测量。在±3 T范围内施加磁场后,非极性共线反铁磁结构会导致较大的线性磁电效应,并具有相当大的耦合系数。施加的电场可以引起相反的线性磁电效应,从而实现铁电的磁场控制和磁的电场控制。此外,更高的磁场(> 3 T)可引起从初始共线反铁磁结构的变磁过渡到倾斜结构,产生大的铁磁磁化高达7.0μ fu -1。此外,新的自旋结构可以破坏空间反转对称性,产生铁电极化,从而导致铁磁和铁电与较大的铁磁分量耦合。

更新日期:2019-09-26
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