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2D MXenes as Co-catalysts in Photocatalysis: Synthetic Methods
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2019-09-21 , DOI: 10.1007/s40820-019-0309-6
Yuliang Sun 1, 2 , Xing Meng 1, 2, 3 , Yohan Dall'Agnese 4 , Chunxiang Dall'Agnese 1 , Shengnan Duan 1, 2 , Yu Gao 1, 2 , Gang Chen 1, 2 , Xiao-Feng Wang 1, 2
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Since their seminal discovery in 2011, two-dimensional (2D) transition metal carbides/nitrides known as MXenes, that constitute a large family of 2D materials, have been targeted toward various applications due to their outstanding electronic properties. MXenes functioning as co-catalyst in combination with certain photocatalysts have been applied in photocatalytic systems to enhance photogenerated charge separation, suppress rapid charge recombination, and convert solar energy into chemical energy or use it in the degradation of organic compounds. The photocatalytic performance greatly depends on the composition and morphology of the photocatalyst, which, in turn, are determined by the method of preparation used. Here, we review the four different synthesis methods (mechanical mixing, self-assembly, in situ decoration, and oxidation) reported for MXenes in view of their application as co-catalyst in photocatalysis. In addition, the working mechanism for MXenes application in photocatalysis is discussed and an outlook for future research is also provided.
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中文翻译:

2D MXenes在光催化中作为助催化剂:合成方法

自2011年开创性地发现以来,构成大型2D材料家族的被称为MXene的二维(2D)过渡金属碳化物/氮化物由于其出色的电子性能而被瞄准各种应用。与某些光催化剂结合用作辅助催化剂的MXenes已应用于光催化系统中,以增强光生电荷的分离,抑制快速的电荷复合,并将太阳能转化为化学能或将其用于有机化合物的降解。光催化性能在很大程度上取决于光催化剂的组成和形态,而光催化剂的组成和形态又取决于所用的制备方法。在这里,我们回顾了四种不同的合成方法(机械混合,自组装,原位装饰,鉴于MXene在光催化中作为助催化剂的应用,对MXenes进行了报道。此外,讨论了MXenes在光催化中的应用机理,并提供了未来的研究前景。
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更新日期:2019-09-21
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