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Coupling Enhanced Oxygen Reduction Reaction Activity from Ag Nanorods-rGO Hybrids
Journal of The Electrochemical Society ( IF 3.9 ) Pub Date : 2019-08-13 , DOI: 10.1149/2.0381913jes
Dong-Xiang Zhu 1 , Shuai Chen 2 , Jian-Li Mi 2 , Chen-Xi Xu 1 , Pai-Feng Luo 1 , Ji-Gui Cheng 1 , Hong-Hai Zhong 1 , Ying-Wei Lu 1
Affiliation  

Ag nanorods-reduced graphene oxide (Ag-rGO) hybrid nanostructures, as an alternative oxygen reduction catalyst to Pt-based materials, have been prepared through a co-reductive method. The electrochemical performance reveal that both the on-set potentials and the limiting diffusion current densities of Ag-rGO samples are comparable to those of commercial Pt/C catalyst, implying that such hybrid nanostructures could be employed in alkaline fuel cells. Both contrast experimental characterizations and energy level analysis indicate that the enhanced oxygen reduction activity of Ag-rGO hybrid nanostructures can be attributed to the strong coupling between Ag nanorods and rGO sheets.

中文翻译:

Ag纳米棒-rGO杂化物的偶联增强的氧还原反应活性

已经通过共还原方法制备了Ag纳米棒还原的氧化石墨烯(Ag-rGO)杂化纳米结构,作为Pt基材料的替代氧还原催化剂。电化学性能表明,Ag-rGO样品的起始电势和极限扩散电流密度均与商用Pt / C催化剂相当,这表明此类杂化纳米结构可用于碱性燃料电池。对比实验表征和能级分析均表明,Ag-rGO杂化纳米结构的增强的氧还原活性可归因于Ag纳米棒与rGO片之间的强耦合。
更新日期:2019-08-15
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