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Sulfonic acid-functionalized polyallylamine (sevelamer) as an efficient reusable strong solid acid catalyst for the synthesis of xanthenes derivatives
BMC Chemistry ( IF 4.6 ) Pub Date : 2019-07-26 , DOI: 10.1186/s13065-019-0609-4
Xian-Liang Zhao 1 , Makombe Shelton 1 , Ke-Fang Yang 2
Affiliation  

Sevelamer (polyallyamine resin)-supported sulfonic acid (S-SO3H) has been prepared from the reaction of sevelamer with chlorosulfonic acid and characterized using FT-IR spectroscopy, scanning electronmicroscopy (SEM) and thermogravimetric analysis (TGA). The catalytic activity of S-SO3H was investigated in the synthesis of 1,8-dioxo-octahydroxanthene derivatives. All of the reactions were fast and gave excellent yields. The catalyst was easily recovered and reused for 5 runs without significant loss of its catalytic activity.

中文翻译:

磺酸功能化聚烯丙胺(司维拉姆)作为有效可重复使用的强固体酸催化剂,用于合成呫吨衍生物

通过司维拉姆与氯磺酸的反应制备了司维拉姆(聚烯丙胺树脂)负载的磺酸(S-SO3H),并使用 FT-IR 光谱、扫描电子显微镜(SEM)和热重分析(TGA)对其进行了表征。研究了S-SO3H在1,8-二氧代-八氢呫吨衍生物合成中的催化活性。所有反应都快速且产率优异。该催化剂很容易回收并重复使用 5 次,其催化活性没有显着损失。
更新日期:2019-07-26
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