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Optical and Physical Probing of Thermal Processes in Semiconductor and Plasmonic Nanocrystals
Annual Review of Physical Chemistry ( IF 14.7 ) Pub Date : 2019-06-07 00:00:00 , DOI: 10.1146/annurev-physchem-042018-052639
Benjamin T. Diroll 1 , Matthew S. Kirschner 2 , Peijun Guo 1 , Richard D. Schaller 1, 2
Affiliation  

This article reviews thermal properties of semiconductor and emergent plasmonic nanomaterials, focusing on mechanisms through which hot carriers and phonons are produced and dissipated as well as the related impacts on optoelectronic properties. Elevated equilibrium temperatures, of particular relevance for implementation of nanomaterials in devices, affect absorptive and radiative transitions as well as emission efficiency that can present reversible and irreversible changes with temperature. In noble metal or doped semiconductor/insulator nanomaterials, hot carriers and lattice heating can substantially influence localized surface plasmon resonances and yield large ultrafast changes in transmission or strongly oscillatory coherences. Transient optical and diffraction characterizations enable nonequilibrium investigations of phonon dynamics and cooling such as lattice expansion and crystal phase stability. Timescales of nanoparticle thermalization with surroundings and transport of heat within films of such materials are also discussed.

中文翻译:


半导体和等离子体纳米晶体中热过程的光学和物理探测

本文回顾了半导体和新兴的等离激元纳米材料的热性能,重点介绍了产生和消散热载流子和声子的机理以及对光电子性能的相关影响。升高的平衡温度,特别是与在设备中使用纳米材料相关的温度,会影响吸收和辐射跃迁以及发射效率,后者会随温度呈现可逆和不可逆的变化。在贵金属或掺杂的半导体/绝缘体纳米材料中,热载流子和晶格加热会显着影响局部表面等离子体激元共振,并产生较大的超快速透射率变化或强烈的振荡相干性。瞬态光学和衍射特性使声子动力学和冷却(例如晶格膨胀和晶体相稳定性)的非平衡研究成为可能。还讨论了纳米颗粒在周围环境中热化的时标以及此类材料薄膜内的热量传递。

更新日期:2019-06-07
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