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Synthesis, self-assembly and applications of functional polymers based on porphyrins
Progress in Polymer Science ( IF 27.1 ) Pub Date : 2019-05-15 , DOI: 10.1016/j.progpolymsci.2019.05.002
Jia Tian , Weian Zhang

Porphyrins and their derivatives have attracted great attention due to their unique properties and diverse functionalities which contribute to their wide applications such as catalysis, solar cells, biomedicine and environmental science. It is interesting to note that porphyrin-containing polymers have recently aroused great interest due to the simultaneous presence of both porphyrinic and polymeric characteristics, especially for porphyrin-containing polymers linked by covalent bonds giving well-defined macromolecular architectures, unique self-assembly morphologies and promising applications. Herein, we summarize the different synthetic strategies and self-assembly protocols adopted in recent years to explore various applications of porphyrin-based functional polymers followed by a brief discussion on the challenges and outlooks for future research.

With the discovery of advanced polymerization techniques such as living/controlled radical polymerization and click chemistry, the synthesis of porphyrin-containing functional polymers with well-defined architectures has been greatly developed. Porphyrin molecules tend to form the aggregates based on the self-assembly driving force of π-π stacking. Much attention has been paid to the self-assembly behavior of porphyrin-containing functional polymers, and various nanostructures have been constructed including nano-sized or micron-sized spheres, vesicles, belts, wires, rings, tubes, and rods. Porphyrin-containing functional polymers, with special photochemical and photophysical properties, present significant applications in photovoltaics, catalysis, biological and biomedicine fields. Particularly, the porphyrin-based photosensitizers for photodynamic therapy, porphyrin-conjugated polymers for solar cell devices, porphyrin-based polymeric nanocomposites in catalysis and chemical adsorption and separation have been widely studied. We hope this review on porphyrin-based functional polymers will be beneficial to researchers and newcomers in related fields.



中文翻译:

基于卟啉的功能聚合物的合成,自组装及其应用

卟啉及其衍生物因其独特的性能和多样化的功能而引起了极大的关注,这些特性及其广泛的应用有助于其广泛应用,例如催化,太阳能电池,生物医学和环境科学。有趣的是,由于同时存在卟啉和聚合物特性,含卟啉的聚合物引起了极大的兴趣,特别是对于通过共价键连接的含卟啉的聚合物,它们给出了明确的大分子结构,独特的自组装形态和有前途的应用程序。在此处,

随着先进聚合技术(例如活性/受控自由基聚合和点击化学)的发现,具有明确结构的含卟啉功能聚合物的合成得到了极大的发展。卟啉分子倾向于基于π-π堆积的自组装驱动力而形成聚集体。已经对含卟啉的功能聚合物的自组装行为给予了很多关注,并且已经构建了各种纳米结构,包括纳米尺寸或微米尺寸的球,囊泡,带,线,环,管和棒。含卟啉的功能性聚合物具有特殊的光化学和光物理性质,目前在光伏,催化,生物和生物医学领域具有重要的应用。特别,广泛研究了用于光动力疗法的基于卟啉的光敏剂,用于太阳能电池装置的卟啉共轭聚合物,催化,化学吸附和分离的基于卟啉的聚合物纳米复合材料。我们希望这篇基于卟啉的功能聚合物的综述将对相关领域的研究人员和新手们有所帮助。

更新日期:2019-05-15
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