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Rapid and sustainable process with low toxicity for cyanation of silver nitrate by DC arc-discharge in presence of acetonitrile
Arabian Journal of Chemistry ( IF 6 ) Pub Date : 2020-02-01 , DOI: 10.1016/j.arabjc.2019.03.003
Ali Reza Molla Ebrahimlo , Parinaz Ghasempoor Soreh

Abstract Use of Direct current (DC) arc-discharge in the chemistry reactions is very novel method. In this technique, the DC arc-discharge as a high-energy source conducts reaction to cleaving of the C-CN bond in acetonitrile and causes the cyanation of silver nitrate. This process due to non-use of cyanide ion can be proposed as a green and sustainable method. The obtained Silver cyanide from this procedure was characterized by its spectroscopic data (FT-IR and XRD). Download : Download high-res image (194KB) Download : Download full-size image

中文翻译:

乙腈存在下直流电弧放电氰化硝酸银的快速、可持续的低毒工艺

摘要 在化学反应中使用直流(DC)电弧放电是一种非常新颖的方法。在该技术中,作为高能量源的直流电弧放电进行反应,使乙腈中的 C-CN 键断裂,并使硝酸银氰化。由于不使用氰化物离子,这个过程可以被提议为一种绿色和可持续的方法。从该过程中获得的氰化银通过其光谱数据(FT-IR 和 XRD)进行表征。下载 : 下载高分辨率图片 (194KB) 下载 : 下载全尺寸图片
更新日期:2020-02-01
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