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Polymers from macrolactones: From pheromones to functional materials
Progress in Polymer Science ( IF 27.1 ) Pub Date : 2019-02-16 , DOI: 10.1016/j.progpolymsci.2019.02.005
James A. Wilson , Zeliha Ates , Robin L. Pflughaupt , Andrew P. Dove , Andreas Heise

Recent advances in the ring-opening polymerization (ROP) of macrolactones (MLs) have afforded access to novel, potentially degradable polymeric materials featuring long aliphatic chains. These developments extend the synthetic robustness and versatility of ROP to a greater range of interesting monomers, many of which can be derived from sustainable or renewable feedstocks, to access polymeric materials boasting a diversity of properties and potential applications. This review discusses current strategies to catalyse the ROP of MLs, comparing and contrasting them with those known for the ROP of small and medium sized lactones, and highlights recent developments in the preparation, functionalization, and application of materials featuring poly(macrolactone)s (PMLs).



中文翻译:

大内酯的聚合物:从信息素到功能材料

大内酯(ML)的开环聚合(ROP)的最新进展使人们能够获得具有长脂族链的新型,潜在可降解的聚合材料。这些进展将ROP的合成坚固性和多功能性扩展到了更多有趣的单体上,其中许多单体可以来自可持续或可再生的原料,从而获得具有多种性能和潜在应用的聚合物材料。这篇综述讨论了催化ML的ROP的当前策略,并将其与中小型内酯的ROP已知的策略进行了比较和对比,并着重介绍了以聚(甲基内酯)为特征的材料的制备,功能化和应用方面的最新进展( PML)。

更新日期:2019-02-16
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