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Sulfur fertilizer based on inverse vulcanization process with soybean oil
Polymer Degradation and Stability ( IF 5.9 ) Pub Date : 2019-02-12 , DOI: 10.1016/j.polymdegradstab.2019.02.011
Stella F. Valle , Amanda S. Giroto , Rodrigo Klaic , Gelton G.F. Guimarães , Caue Ribeiro

Sulfur deficiency in soils has become an increasing concern over the past decades. Despite elemental sulfur (S8) vast utilization as a commercial fertilizer, S8 has to be biologically oxidized for plant assimilation, drastically limiting its efficiency. Therefore, we propose a new fertilizer in which S8 structure is more accessible to oxidizing microorganisms by chemical modification via inverse vulcanization technique, a solvent-free copolymerization method, with soybean oil as comonomer. Sulfur oxidation experiments were performed by A. niger submerged cultivation, confirming that the homogeneous rubbery-like material provides enhanced oxidation, with great potential as multifunctional sulfur-fertilizer.



中文翻译:

基于大豆油反硫化工艺的硫磺肥料

在过去的几十年中,土壤中的硫缺乏已引起越来越多的关注。尽管元素硫(S 8)广泛用作商业肥料,但S 8必须被生物氧化以吸收植物,从而极大地限制了其效率。因此,我们提出了一种新肥料,其中以大豆油为共聚单体的逆硫化技术,无溶剂共聚法通过化学修饰使S 8结构更易于被氧化微生物氧化。通过黑曲霉(A.niger)的深层培养进行了硫的氧化实验,证实了均匀的橡胶状材料提供了增强的氧化作用,具有作为多功能硫肥料的巨大潜力。

更新日期:2019-02-12
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