Homochiral iron(ii)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel†,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Homochiral iron(ii)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel†
Chemical Communications ( IF 4.9 ) Pub Date : 2019-02-08 00:00:00 , DOI: 10.1039/c9cc00506d
Jia-Ge Jia _{1,

2,

3,

4,

5} , Jian-Shen Feng _{1,

2,

3,

4,

5} , Xin-Da Huang _{1,

2,

3,

4,

5} , Song-Song Bao _{1,

2,

3,

4,

5} , Li-Min Zheng _{1,

2,

3,

4,

5}

Affiliation

Homochiral iron(II)-based nanotubular metal phosphonates (R)- and (S)-[Fe(pemp)(H₂O)₂] [pemp²⁻ = (R)- or (S)-(1-phenylethylamino)methylphosphonate] are reported showing metamagnetism at low temperature. The dehydrated product features coordinatively unsaturated and redox-active metal ion sites that enable it to strongly bind nitric oxide at room temperature.

中文翻译：

基于手性铁（ii）的金属有机纳米管：密闭通道中的超磁性和选择性一氧化氮吸附†

基于手性铁（II）的纳米管金属膦酸酯（R）-和（S）-[Fe（pemp）（H ₂ O）₂ ] [pemp ²⁻ =（R）-或（S）-（1-苯基乙基氨基）据报道[甲基膦酸酯]在低温下表现出超磁性。脱水产品具有配位不饱和和氧化还原活性的金属离子位点，使其能够在室温下牢固结合一氧化氮。

更新日期：2019-02-08

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南

全部期刊列表>>