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Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt†
Dalton Transactions ( IF 4 ) Pub Date : 2017-02-09 00:00:00 , DOI: 10.1039/c7dt00180k
Elnaz Hobbollahi 1, 2, 3, 4 , Manuela List 2, 3, 4, 5 , Benjamin Hupp 6, 7, 8, 9 , Fabian Mohr 9, 10, 11, 12, 13 , Raphael J. F. Berger 4, 14, 15, 16, 17 , Andreas Steffen 6, 7, 8, 9 , Uwe Monkowius 1, 2, 3, 4
Affiliation  

In the trinuclear, heterometallic cluster compound [Au2CuCl2(P∩N)2]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin–orbit coupling and short emission lifetimes, which are competitive to PtII- and IrIII-based emitters.

中文翻译:

[Au 2 CuCl 2(P∩N)2 ] PF 6型盐中的高效冷白光发射

在三核,杂金属簇化合物[Au 2 CuCl 2(P∩N)2 ] PF 6的亲金属相互作用中,由于至少两个热不平衡的发射三重态而导致非常有效的冷白光发射(其中一个是主要是Cu→py和Au→py的另一个特征),具有优异的自旋轨道耦合和较短的发射寿命,与基于Pt II和Ir III的发射器相比具有竞争力。
更新日期:2017-02-09
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