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In situ growth of CoFe-prussian blue analog nanospheres on ferrocene-functionalized ultrathin layered Ti3C2Tx MXene frameworks for efficient detection of xanthine
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2023-06-01 , DOI: 10.1016/j.cej.2023.143866
Mingyue Chu , Ying Wang , Jianjiao Xin , Li Zhang , Yikun Liu , Guixin Yang , Huiyuan Ma , Yingji Wang , Haijun Pang , Xinming Wang

A funky electrochemical sensor for xanthine catching was proposed by growing CoFe-Prussian blue analogs (CoFe-PBA) in situ on ferrocene functionalized Ti3C2Tx MXene (Fc-Ti3C2Tx), denoted as CoFe-PBA/Fc-Ti3C2Tx. In this sensor, introduction of unique thin-layer structure Ti3C2Tx MXene as the interlayer spacers to accommodate ferrocene and CoFe-PBA prevented the restacking of MXene and CoFe-PBA, meanwhile gained higher conductivity. The CoFe-PBA/Fc-Ti3C2Tx was observed by SEM and TEM to possess abundant heteroatom-functionalized multiple-layers structure, and it was therefore endowed with a faster electron transfer rate and a greater electrochemically active surface area. Furthermore, the sensor was investigated using differential pulse voltammetr (DPV) and superiorelectrochemical sensing performance for xanthine detection was achieved with rather wide linear range (3 × 10−8 to 1.007 × 10−3 M), a remarkably low detection limit (0.002 μM), and superior stability. The recovery rate of real sample analysis was acceptable, demonstrating the viability of using this electrochemical sensor in real applications.



中文翻译:

在二茂铁功能化的超薄层状 Ti3C2TX MXene 框架上原位生长 CoFe-普鲁士蓝模拟纳米球,用于有效检测黄嘌呤

通过在二茂铁功能化的 Ti 3 C 2 T x MXene (Fc-Ti 3 C 2 T x ) 上原位生长 CoFe-普鲁士蓝类似物 (CoFe-PBA),提出了一种用于黄嘌呤捕获的时髦电化学传感器,表示为 CoFe- PBA/ Fc-Ti 3 C 2 T x。在该传感器中,引入独特的薄层结构 Ti 3 C 2 T x MXene 作为层间间隔物以容纳二茂铁和 CoFe-PBA,防止了 MXene 和 CoFe-PBA 的重新堆叠,同时获得了更高的导电性。CoFe-PBA/Fc-Ti 3 C 2 T xSEM和TEM观察到具有丰富的杂原子功能化多层结构,因此具有更快的电子转移速率和更大的电化学活性表面积。此外,该传感器使用差分脉冲伏安法 (DPV) 进行了研究,实现了黄嘌呤检测的优异电化学传感性能,具有相当宽的线性范围(3 × 10 -8至 1.007 × 10 -3 M),非常低的检测限(0.002 μM) ), 以及优越的稳定性。实际样品分析的回收率是可以接受的,证明了在实际应用中使用这种电化学传感器的可行性。

更新日期:2023-06-04
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