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Copper-Catalyzed Synthesis of S–S Bond-Containing Silanols from SCBs and Trisulfide-1,1-dioxides
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2023-05-26 , DOI: 10.1021/acs.joc.2c02968
Ying Chen 1 , Fei Wang 1 , Weidong Rao 2 , Shusu Shen 3 , Daopeng Sheng 4 , Shun-Yi Wang 1
Affiliation  

In this work, an efficient method for the copper-catalyzed ring-opening hydrolysis of silacyclobutanes to silanols was developed. This strategy has the advantages of friendly reaction conditions, simple operation, and good functional group compatibility. No additional additives are required in the reaction, and the S–S bond can also be introduced into the organosilanol compounds in one step. Furthermore, the success at the gram scale demonstrates the great potential of the developed protocol for practical industrial applications.

中文翻译:

铜催化 SCB 和 1,1-二氧化物三硫化物合成含 S-S 键的硅烷醇

在这项工作中,开发了一种铜催化硅杂环丁烷开环水解成硅烷醇的有效方法。该策略具有反应条件友好、操作简单、官能团相容性好的优点。该反应不需要额外的添加剂,并且S-S键也可以一步引入到有机硅烷醇化合物中。此外,克级的成功证明了所开发的协议在实际工业应用中的巨大潜力。
更新日期:2023-05-26
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