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Photocatalytic Transfer Hydrogenation Reactions Using Water as the Proton Source
ACS Catalysis ( IF 12.9 ) Pub Date : 2023-05-21 , DOI: 10.1021/acscatal.3c00326
En Zhao, Wenjun Zhang, Lin Dong, Radek Zbořil, Zupeng Chen

Transfer hydrogenation using liquid hydrogen carriers as the direct proton sources under mild conditions has received extensive attention in the research area of organic synthesis. The emerging photocatalytic water-donating transfer hydrogenation (PWDTH) is a promising alternative over the conventional hydrogenation technology due to the advantages of being eco-friendly. This paper focuses on the recent advances in the rising and rapidly developing field of PWDTH reactions, devoted to elucidating the mechanism of the hydrogen transfer process and rationalizing the design principles of efficient photocatalysts. Finally, the current challenges and future opportunities are described.

中文翻译:

以水为质子源的光催化转移加氢反应

在温和条件下以液态氢载体为直接质子源的转移氢化反应在有机合成研究领域受到广泛关注。新兴的光催化供水转移氢化(PWDTH)由于具有环保优势,是传统氢化技术的一种有前途的替代方案。本文重点关注新兴和快速发展的 PWDTH 反应领域的最新进展,致力于阐明氢转移过程的机理和合理化高效光催化剂的设计原则。最后,描述了当前的挑战和未来的机遇。
更新日期:2023-05-21
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