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Triethylamine-Mediated Transformation of Phosphonates into Phosphonamidates
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2023-05-10 , DOI: 10.1002/ejoc.202300172
Simon Backx, Andreas Dejaegere, Andreas Simoens, Jef Van de Poel, Dorota Krasowska, Christian V. Stevens, Sven Mangelinckx

This work presents a flexible, straightforward methodology to synthesize phosphonamidates starting from commonly available phosphonates, and demonstrates the use of phosphonylaminium salts to mediate the harsh reactivity of phosphonochloridates. Our methodology is demonstrated on primary amines, secondary amines, ammonium acetate, aniline derivatives and different phosphonate diesters.

中文翻译:

三乙胺介导的膦酸酯转化为膦酰胺

这项工作提出了一种灵活、简单的方法,从常用的膦酸酯开始合成膦酰胺酯,并演示了使用膦酰胺盐来介导膦酰氯酸酯的严酷反应性。我们的方法在伯胺、仲胺、乙酸铵、苯胺衍生物和不同的膦酸二酯上进行了论证。
更新日期:2023-05-10
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