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Experimental study on solubility of CO2 and CH4 in the ionic liquid 1-benzyl-3-methylimidazolium nitrate
The Journal of Supercritical Fluids ( IF 3.9 ) Pub Date : 2023-04-29 , DOI: 10.1016/j.supflu.2023.105963
Mojtaba Mirzaei , Ali Sharifi , M. Saeed Abaee

The solubility of two single gases, CO2 and CH4, was measured in the ionic liquid 1-benzyl-3-methylimidazolium nitrate ([Bzmim][NO3]), at temperatures ranging from 298.15 to 343.15 K and pressures up to 4.52 MPa for CO2 and 4.22 MPa for CH4, where the CO2 and CH4 mole fractions reached to 0.29 and 0.09, respectively. The solubility measurements were performed in a stainless steel equilibrium cell. Under the experimental conditions, CO2 showed a significantly higher solubility than CH4. The CO2 solubility decreased in [Bzmim][NO3], when temperature was raised, while in the case of CH4, the solubility increased slightly with the increase of temperature. In addition, the CO2 solubility was compared to that of CH4 using the ratio of the Henry’s constants of CH4 over that of CO2. The changes in ideal selectivity vs temperature showed that by the increase in temperature the ideal selectivity decreases.



中文翻译:

CO2和CH4在离子液体硝酸1-苄基-3-甲基咪唑鎓中溶解度的实验研究

在离子液体 1-benzyl-3-methylimidazolium nitrate ([Bzmim][NO 3 ])中测量了两种单一气体 CO 2和 CH 4的溶解度,温度范围为 298.15 至 343.15 K,压力高达 4.52 CO 2的MPa和CH 4的4.22 MPa ,其中CO 2和CH 4的摩尔分数分别达到0.29和0.09。溶解度测量是在不锈钢平衡池中进行的。在实验条件下,CO 2 的溶解度明显高于CH 4。CO 2在[Bzmim][NO 3中的溶解度降低],当温度升高时,CH 4的溶解度随着温度的升高而略有增加。此外,使用CH 4的亨利常数与CO 2的亨利常数之比将CO 2溶解度与CH 4的溶解度进行比较。理想选择性随温度的变化表明,随着温度的升高,理想选择性会降低。

更新日期:2023-04-29
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