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Reactivity of Hypervalent Iodine(III) Reagents Bearing Transferable N-Based Groups
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2023-04-25 , DOI: 10.1002/ejoc.202300109
João Macara 1 , Catarina Caldeira 1 , Diogo L. Poeira 1 , Maria M Marques 2
Affiliation  

Electrophilic sources of nitrogen-based groups have been known for many decades and are of great synthetic importance. Hypervalent iodine reagents bearing N-containing groups have emerged as an alternative to classical electrophilic amination reactions, and are capable of transferring a wide diversity of nitrogen-containing functional groups to organic molecules. The reactivity of these reagents as well as the mechanism and scope of the reactions are reviewed.

中文翻译:

带有可转移 N 基基团的高价碘 (III) 试剂的反应性

氮基基团的亲电源已为人所知数十年,并且具有重要的合成重要性。带有含氮基团的高价碘试剂已成为经典亲电胺化反应的替代品,并且能够将多种含氮官能团转移到有机分子上。综述了这些试剂的反应性以及反应的机理和范围。
更新日期:2023-04-25
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