Synergistic integration between carbon matrix and 2D MXene brings up great creativity towards more opportunity of versatile serving scenario for MXene-based hybrid materials, especially in realms like electrochemical energy storage, photo-/electrocatalysis water splitting, electromagnetic waves adsorption, sensing and so on. Multidimensional carbonaceous matrix, from zero-dimension (0D) to larger scales of 3D counterparts, building various heterostructure configuration with 2D MXene, could cultivate personas for different targets and further maximizing MXene intrinsic strength of in terms of layered structure and unique properties. In our review, we present a comprehensive discussion on miscellaneous structural integration of carbon matrix and MXene, including designing principles, synthetic routes, as well as internal correlation between two components. Meanwhile, we analyze and elaborate the textural features and structure–property relationships of 2D MXene-based composites with 0D, 1D, 2D and 3D multidimensional carbon matrix. At last, to fulfill future development and application foreground, we put forward subsistent challenge and noteworthy research perspectives of MXene-based and corresponding hybridization with carbonaceous matrix with different dimensionalities.

碳基质和二维 MXene 之间的协同整合为基于 MXene 的混合材料提供了更多的多功能服务场景机会，特别是在电化学储能、光/电催化水分解、电磁波吸附、传感等领域。多维碳质基质，从零维 (0D) 到更大尺度的 3D 对应物，使用 2D MXene 构建各种异质结构配置，可以针对不同目标培养角色，并进一步最大化 MXene 在分层结构和独特性能方面的内在强度。在我们的综述中，我们对碳基质和 MXene 的各种结构整合进行了全面讨论，包括设计原则、合成路线、以及两个组件之间的内部相关性。同时，我们分析并阐述了具有 0D、1D、2D 和 3D 多维碳基体的 2D MXene 基复合材料的结构特征和结构-性能关系。最后，为了满足未来的发展和应用前景，我们提出了基于 MXene 和相应的不同维度碳质基质杂化的存在挑战和值得注意的研究前景。