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Experimental investigation of porous carbon for cooling and desalination applications
npj Clean Water ( IF 11.4 ) Pub Date : 2023-01-11 , DOI: 10.1038/s41545-022-00211-z
Ahmed S. Alsaman , M. Salem Ahmed , E. M. M. Ibrahim , Ehab S. Ali , A. M. Farid , Ahmed A. Askalany

Adsorption cooling and desalination (ACD) system presents a solution for water, energy, and environmental dilemma. This study expresses an enhancement of adsorption system performance in terms of cooling and desalination effects by improving an activated carbon Maxsorb III (Max) as an adsorbent. Max has been initially treated with HCl. Then, it has been activated by impregnating it in salt hydrates ((NH4)2CO3). Characterization methods, including XRD, N2 and water adsorption isotherm, and water adsorption kinetics have been conducted for raw Max, treated Max, and activated Max with (NH4)2CO3. The experimental values have been fitted with the Dubinin & Astakhov equilibrium model for isotherm and the model of linear driving force for kinetics. These fitted parameters have been utilized in a previously validated model to estimate adsorption cooling-desalination system performance with and without heat recovery. Max/(NH4)2CO3 achieves a water uptake of 0.53 kgH2O.kg-1. Max/(NH4)2CO3 produces 13.2 m3.ton-1 of freshwater per day with a specific cooling power of 373 W.kg-1 and 0.63 COP. Also, the freshwater reaches 22.5 m3.ton-1 of Max/(NH4)2CO3 per day with condenser-evaporator heat recovery. These results indicate the potential of utilizing the Max material in dual cooling and desalination applications to achieve double what silica gel can offer.



中文翻译:

用于冷却和海水淡化应用的多孔碳的实验研究

吸附冷却和海水淡化 (ACD) 系统为水、能源和环境难题提供了解决方案。该研究通过改进活性炭 Maxsorb III (Max) 作为吸附剂,在冷却和脱盐效果方面表达了吸附系统性能的增强。Max 最初用 HCl 处理过。然后,通过将其浸渍在盐水合物 ((NH 4 ) 2 CO 3 ) 中对其进行活化。表征方法,包括 XRD、N 2和水吸附等温线,以及水吸附动力学,已对原始 Max、处理过的 Max 和使用 (NH 4 ) 2 CO 3活化的 Max 进行了分析. 实验值已拟合等温线的Dubinin & Astakhov 平衡模型和动力学的线性驱动力模型。这些拟合参数已在先前验证的模型中使用,以估计有和没有热回收的吸附冷却-海水淡化系统性能。Max/(NH 4 ) 2 CO 3达到0.53 kg H2O .kg -1的吸水率。Max/(NH 4 ) 2 CO 3每天产生13.2 m 3 .ton -1淡水,特定冷却功率为373 W.kg -1和0.63 COP。此外,淡水达到 22.5 m 3.ton -1 of Max/(NH 4 ) 2 CO 3每天,带冷凝器-蒸发器热回收。这些结果表明,在双重冷却和海水淡化应用中使用 Max 材料可以实现硅胶所能提供的两倍效果。

更新日期:2023-01-12
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