The development of the liquid microjet technique by Faubel and co-workers has enabled the investigation of high vapor pressure liquids and solutions utilizing high-vacuum methods. One such method is photoelectron spectroscopy (PES), which allows one to probe the electronic properties of a sample through ionization in a state-specific manner. Liquid microjets consisting of pure solvents and solute–solvent systems have been studied with great success utilizing PES and, more recently, time-resolved PES (TRPES). Here, we discuss progress made over recent years in understanding the solvation and excited state dynamics of the solvated electron and nucleic acid constituents (NACs) using these methods, as well as the prospect for their future.

中文翻译：

---

液体喷射时间分辨光电子能谱研究非绝热动力学

Faubel 及其同事开发的液体微喷射技术使利用高真空方法研究高蒸气压液体和溶液成为可能。一种这样的方法是光电子能谱 (PES)，它允许人们以状态特定的方式通过电离来探测样品的电子特性。使用 PES 和最近的时间分辨 PES (TRPES) 研究了由纯溶剂和溶质-溶剂系统组成的液体微射流，并取得了巨大成功。在这里，我们讨论了近年来在使用这些方法理解溶剂化电子和核酸成分 (NAC) 的溶剂化和激发态动力学方面取得的进展，以及它们的未来前景。