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Spectroscopic characteristics and Judd-Ofelt analysis of Pr:GdScO3 crystal
Journal of Luminescence ( IF 3.6 ) Pub Date : 2022-12-08 , DOI: 10.1016/j.jlumin.2022.119599
Na Li , Jian Liu , Ruiqin You , Yanyan Xue , Xiaodong Xu , Jun Xu

The polarization absorption spectra of Pr3+-doped GdScO3 have been measured. Polarized emission spectra and fluorescence decay from the 3P0 upper level have been investigated. The strongest absorption peaks are located at 448 nm for a, b and c polarization, the absorption cross sections are 1.29 × 10−20 cm2, 0.98 × 10−20 cm2 and 1.57 × 10−20 cm2, respectively. The maximum emission cross section is located at 662 nm, which is 18.55 × 10−20 cm2 (a polarization), 12.74 × 10−20 cm2 (b polarization) and 22.41 × 10−20 cm2 (c polarization), and the FWHM is 10.02 nm, 9.38 nm and 10.14 nm, respectively. The fluorescence lifetime of 3P0 level is 12.39 μs. Those results indicated that Pr3+-doped GdScO3 crystal grown by the Czochralski method is a potential laser medium for visible laser operation.



中文翻译:

Pr:GdScO3晶体的光谱特性及Judd-Ofelt分析

测量了Pr 3+掺杂的GdScO 3的偏振吸收光谱。已经研究了3 P 0上层的偏振发射光谱和荧光衰减。a、b、c偏振的最强吸收峰位于448nm处,吸收截面分别为1.29×10 -20  cm 2、0.98×10 -20  cm 2和1.57×10 -20  cm 2。最大发射截面位于 662 nm,即 18.55 × 10 -20  cm 2(极化),12.74 × 10 -20  cm 2 (b偏振)和22.41×10 -20  cm 2 (c偏振),FWHM分别为10.02nm、9.38nm和10.14nm。3 P 0能级的荧光寿命为12.39 μs。这些结果表明,通过直拉法生长的 Pr 3+掺杂的 GdScO 3晶体是用于可见激光操作的潜在激光介质。

更新日期:2022-12-08
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