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Pyridine-Boryl Radical Mediated Decarboxylative Homolytic Substitution of N-hydroxyphthalimide Ester with Ar2X2 (X=S, Se)
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2022-12-01 , DOI: 10.1002/ejoc.202201290
Jia Cao 1 , Liu zhou Gao 1 , Guo qiang Wang 1 , Shuhua Li 2
Affiliation  

A pyridine-catalyzed decarboxylative C−S/Se bonds constructions with the broadly available N-hydroxyphthalimide esters and disulfides/diselenides (Ar2X2, X=S or Se) has been developed using bis(pinacolato)diboron as the reductant. This synthetic method features mild reaction conditions, operational simplicity and good functional-group tolerance.

中文翻译:

吡啶-硼基自由基介导的 N-羟基邻苯二甲酰亚胺酯的脱羧均溶取代与 Ar2X2 (X=S, Se)

使用双(频哪醇)二硼作为还原剂,开发了一种吡啶催化的脱羧 C−S/Se 键结构与广泛可用的 N-羟基邻苯二甲酰亚胺酯和二硫化物/二硒化物(Ar 2 X 2 ,X=S 或 Se)。该合成方法反应条件温和、操作简单、官能团耐受性好。
更新日期:2022-12-01
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