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One-Pot Synthesis of 4-Thiocyanato-1H-pyrazoles through Electrochemical Multicomponent Thiocyanation under Metal- and Oxidant-Free Conditions
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2022-12-01 , DOI: 10.1002/ejoc.202201278
Ying Zhang, Sen Xu, Yutao Zhu, Qingyu Xu, Huanjie Gao, Zeyao Liang, Xiaoquan Yao

Herein, an electrochemical oxidative multicomponent thiocyanation by using ammonium thiocyanate as thiocyano source was described in an undivided cell under mild conditions. A broad spectrum of 4-thiocyanato-1H-pyrazoles were synthesized through the functionalization of the pyrazole intermediates.

中文翻译:

无金属无氧化剂条件下电化学多组分硫氰化一锅法合成 4-Thiocyanato-1H-pyrazoles

在此,描述了在温和条件下在未分隔的电池中使用硫氰酸铵作为硫氰源的电化学氧化多组分硫氰化反应。通过吡唑中间体的功能化,合成了广谱的 4-thiocyanato-1 H -pyrazoles。
更新日期:2022-12-01
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