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Low-temperature preparation of novel fluoro-fluoro semi-interpenetrating polymer networks as a strong, tough and safe polymer binder for PBX
Polymer ( IF 4.6 ) Pub Date : 2022-11-25 , DOI: 10.1016/j.polymer.2022.125562
Chao Deng , HuiHui Liu , YuTao Cui , XiaoNan Zhu , YongPing Bai , Zhen Hu

This work provides an energy saving strategy for strengthening and toughening fluoroelastomer (linear F2314) by using liquid fluorine rubber (HTLF-700). A series of semi-interpenetrating polymer networks based on the F2314 and the crosslinked HTLF-700 (namely F23-CLF-X semi-IPNs) were firstly prepared at low temperatures and characterized using FTIR, SEM, EDS, TGA, DSC, DMA and tensile testing et al. The as-prepared F23-CLF-30 semi-IPNs film possessed well interpenetrating co-continuous phases and thus exhibited prominent mechanical performance with the higher tensile strength (33.0 MPa), the larger elongation at break (165.0%), the better mechanical stability at high and low temperature shock and the higher high-temperature creep resistance compared with the F2314. Meanwhile, the arc Brazilian test indicates that F23-CLF semi-IPNs could be a promising candidate as a polymer binder for polymer bonded explosive (PBX).



中文翻译:

低温制备新型氟-氟半互穿聚合物网络作为 PBX 的强韧安全聚合物粘合剂

这项工作为使用液态氟橡胶 (HTLF-700) 强化和增韧氟橡胶 (线性 F2314) 提供了一种节能策略。首先在低温下制备了一系列基于 F2314 和交联的 HTLF-700 的半互穿聚合物网络(即 F23-CLF-X semi-IPNs),并使用 FTIR、SEM、EDS、TGA、DSC、DMA 和拉伸试验等。所制备的 F23-CLF-30 半 IPNs 薄膜具有良好的互穿共连续相,因此表现出突出的机械性能,具有更高的拉伸强度(33.0 MPa)、更大的断裂伸长率(165.0%)、更好的机械稳定性与 F2314 相比,在高低温冲击和高温抗蠕变性能方面具有更高的性能。同时,

更新日期:2022-11-30
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