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Superconductivity enhancement in polar metal regions of Sr0.95Ba0.05TiO3 and Sr0.985Ca0.015TiO3 revealed by systematic Nb doping
npj Quantum Materials ( IF 5.7 ) Pub Date : 2022-11-30 , DOI: 10.1038/s41535-022-00524-9
Yasuhide Tomioka , Naoki Shirakawa , Isao H. Inoue

Two different ferroelectric materials, Sr0.95Ba0.05TiO3 and Sr0.985Ca0.015TiO3, can be turned into polar metals with broken centrosymmetry via electron doping. Systematic substitution of Nb5+ for Ti4+ has revealed that these polar metals both commonly show a simple superconducting dome with a single convex shape. Interestingly, the superconducting transition temperature Tc is enhanced more strongly in these polar metals when compared with the nonpolar matrix Sr(Ti, Nb)O3. The maximum Tc reaches 0.75 K, which is the highest reported value among the SrTiO3-based families to date. However, the Tc enhancement is unexpectedly lower within the vicinity of the putative ferroelectric quantum critical point. The enhancement then becomes much more prominent at locations further inside the dilute carrier-density region, where the screening is less effective. These results suggest that centrosymmetry breaking, i.e., the ferroelectric nature, does not kill the superconductivity. Instead, it enhances the superconductivity directly, despite the absence of strong quantum fluctuations.



中文翻译:

系统掺杂 Nb 揭示了 Sr0.95Ba0.05TiO3 和 Sr0.985Ca0.015TiO3 极性金属区域的超导性增强

两种不同的铁电材料Sr 0.95 Ba 0.05 TiO 3和Sr 0.985 Ca 0.015 TiO 3通过电子掺杂可以变成中心对称性破缺的极性金属。用 Nb 5+系统替代Ti 4+表明,这些极性金属通常都显示出具有单个凸形的简单超导圆顶。有趣的是,与非极性基体 Sr(Ti, Nb)O 3相比,这些极性金属的超导转变温度Tc增强得更强烈。最大Tc _达到 0.75 K,这是迄今为止基于SrTiO 3的家族中报道的最高值。然而,在假定的铁电量子临界点附近,T c增强出人意料地较低。然后,在稀载流子密度区域更远的位置,屏蔽效果较差的位置,增强变得更加突出。这些结果表明,中心对称破缺,即铁电性质,不会破坏超导性。相反,它直接增强了超导性,尽管没有强烈的量子涨落。

更新日期:2022-11-30
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