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Electrochemical behavior of gold, palladium and platinum as inert anode materials for molten chloride electrolysis
Electrochimica Acta ( IF 6.6 ) Pub Date : 2022-11-23 , DOI: 10.1016/j.electacta.2022.141598
J. Pertuiset , M. Gibilaro , O. Lemoine , P. Chamelot , G. Bourges , L. Massot

Electrochemical behavior of gold, palladium and platinum as anode materials was studied in a molten chloride media CaCl2 – CaO (0–2 wt%) at 850 °C in order to determine the feasibility of their use as oxygen evolving anodes for electro-deoxidation processes such as the Fray-Farthing-Chen (FFC) Cambridge and Ono and Suzuki (OS) processes. Linear sweep voltammetry measurements and constant current electrolyses were conducted in line with oxygen analysis and mass variation measurements to identify anodic reactions that can occur. It was found that oxygen evolution is possible on gold anode but the metal also undergoes a degradation due to gold chloride AuClx formation. Palladium has to form an oxide layer on its surface to evolve oxygen but is also damaged by PdClx formation. Platinum is the most interesting metal as O2 gas can be produced without damaging the material with a good control of electrolysis conditions such as current density and CaO concentration.



中文翻译:

金、钯和铂作为熔融氯化物电解惰性阳极材料的电化学行为

在 850 °C 的熔融氯化物介质 CaCl 2 – CaO (0–2 wt%) 中研究了金、钯和铂作为阳极材料的电化学行为,以确定它们用作电脱氧放氧阳极的可行性Fray-Farthing-Chen (FFC) Cambridge 和 Ono and Suzuki (OS) 工艺等工艺。线性扫描伏安法测量和恒流电解与氧分析和质量变化测量一致,以识别可能发生的阳极反应。据发现,在金阳极上可能会析出氧气,但金属也会因氯化金 AuCl x的形成而发生降解。钯必须在其表面形成氧化层以释放氧气,但也会被 PdCl x损坏形成。铂是最有趣的金属,因为可以在不损坏材料的情况下产生 O 2气体,同时很好地控制电解条件(例如电流密度和 CaO 浓度)。

更新日期:2022-11-23
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