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Oxygen vacancy-engineered ultrathin NiCo2O4 nanosheet arrays derived from MOFs as an advanced electrode for supercapacitors
Dalton Transactions ( IF 4 ) Pub Date : 2022-11-23 , DOI: 10.1039/d2dt03044f
Qingqing Zhao 1 , Kai Tao 1 , Lei Han 1
Affiliation  

To overcome the poor electronic conductivity and slow ion transport of NiCo2O4, ultrathin nanosheet arrays with oxygen vacancies are constructed by a facile NaBH4 reduction method using a bimetallic MOF as the precursor. Benefiting from the advantages of highly exposed surface area and short paths for charge transport of ultrathin 2D nanosheets, as well as the improved electronic conductivity arising from oxygen vacancies, the optimal 0.1-Ov-NiCo2O4/NF electrode shows excellent electrochemical performance, largely outperforming pristine NiCo2O4/NF.

中文翻译:

源自 MOF 的氧空位工程超薄 NiCo2O4 纳米片阵列作为超级电容器的高级电极

为了克服 NiCo 2 O 4电子导电性差和离子传输缓慢的问题,采用双金属 MOF 作为前体,通过简便的 NaBH 4还原方法构建了具有氧空位的超薄纳米片阵列。得益于超薄二维纳米片的高暴露表面积和短电荷传输路径的优势,以及氧空位引起的电子电导率的提高,最佳的0.1-O v -NiCo 2 O 4 /NF电极显示优异电化学性能, 大大优于原始 NiCo 2 O 4 /NF。
更新日期:2022-11-23
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