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Antiferromagnetic Order in the Rare-Earth Halide Perovskites CsEuBr3 and CsEuCl3
Chemistry of Materials ( IF 8.6 ) Pub Date : 2022-11-15 , DOI: 10.1021/acs.chemmater.2c03051
Daniel B. Straus 1 , Tomasz Klimczuk 2, 3 , Xianghan Xu 1 , Robert J. Cava 1
Affiliation  

Bulk CsEuBr3 and CsEuCl3 are experimentally shown to be magnetic semiconductors that order antiferromagnetically at Néel temperatures of 2.0 K and 1.0 K, respectively. Given that nanoparticles and thin films of CsEuCl3 have been reported to order ferromagnetically at a similar temperature, our observation of antiferromagnetic ordering in CsEuBr3 and CsEuCl3 expands the possible applications of halide perovskites to now include spintronic devices where both ferromagnetic and antiferromagnetic devices can be fabricated from a single material. The conclusion that CsEuCl3 can be used as a switchable magnetic material is also supported by our density-functional theory calculations.

中文翻译:

稀土卤化物钙钛矿 CsEuBr3 和 CsEuCl3 中的反铁磁序

块状 CsEuBr 3和 CsEuCl 3经实验证明是磁性半导体,分别在 2.0 K 和 1.0 K 的奈尔温度下以反铁磁方式排列。鉴于已报道CsEuCl 3的纳米粒子和薄膜在相似温度下进行铁磁排序,我们对 CsEuBr 3和 CsEuCl 3中反铁磁排序的观察扩展了卤化物钙钛矿的可能应用,现在包括自旋电子器件,其中铁磁和反铁磁器件都可以由单一材料制成。我们的密度泛函理论计算也支持了CsEuCl 3可以用作可转换磁性材料的结论。
更新日期:2022-11-15
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