Zr-Carbide promoted Methane Dry Reforming on Ni_xZr_y: Graphitic deposits anti-segregate into Ni⁰ nanoparticles to provide restored CH₄ adsorption sites and near-surface/dissolved C atoms, which migrate toward the Ni⁰/ZrO₂ interface and induce local Zr_xC_y formation. The resulting oxygen-deficient carbidic phase boundary sites assist in kinetically enhanced CO₂ activation toward CO(g).

中文翻译：

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碳化锆介导镍-锆催化剂上的抗结焦甲烷干重整

_{Zr-Carbide 促进甲烷在 Ni x} Zr _y上的干法重整：石墨沉积物反偏析成 Ni ⁰纳米颗粒，以提供恢复的 CH ₄吸附位点和近表面/溶解的 C 原子，这些原子向 Ni ⁰ /ZrO ₂界面迁移并诱导局部 Zr _x C _y形成。由此产生的缺氧碳化物相边界位点有助于在动力学上增强 CO ₂对 CO(g) 的活化。