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Nitrenoid from Oxime: A Practical Synthesis of Planar Chiral Ferrocenyl Phenanthridines via Nitrene-Involved Ring-Expansion Reaction
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-11-07 , DOI: 10.1002/anie.202215530 Na Li 1 , Biqiong Hong 2 , Jinbo Zhao 3 , Zhenhua Gu 1, 2
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-11-07 , DOI: 10.1002/anie.202215530 Na Li 1 , Biqiong Hong 2 , Jinbo Zhao 3 , Zhenhua Gu 1, 2
Affiliation
A new Grignard reagent-mediated synthesis of ferrocene-based phenanthridines from oximes was developed. The tertiary magnesium-zinc nitrenoid was proposed as the key intermediate, which underwent ring-expansion/rearrangement to form the pyridine skeleton.
中文翻译:
来自肟的 Nitrenoid:通过氮烯参与的扩环反应实用合成平面手性二茂铁基菲啶
开发了一种新的格氏试剂介导的从肟合成二茂铁基菲啶的方法。叔镁-锌类硝氮化合物被认为是关键中间体,它经过扩环/重排形成吡啶骨架。
更新日期:2022-11-07
中文翻译:
来自肟的 Nitrenoid:通过氮烯参与的扩环反应实用合成平面手性二茂铁基菲啶
开发了一种新的格氏试剂介导的从肟合成二茂铁基菲啶的方法。叔镁-锌类硝氮化合物被认为是关键中间体,它经过扩环/重排形成吡啶骨架。