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Perfectly Encoding π-Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-11-07 , DOI: 10.1002/anie.202214848
Xianghe Meng 1 , Xingyu Zhang 2 , Qingxiong Liu 1 , Zhengyang Zhou 3, 4 , Xingxing Jiang 2 , Yonggang Wang 5 , Zheshuai Lin 2 , Mingjun Xia 1
Affiliation  

Improving the arrangement of the planar π-conjugated six-membered-ring (C3N3O3)3− anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) series leads to strong second harmonic generation responses, short UV cutoffs, and moderate birefringence. This finding opens an avenue for designing target materials with balanced linear and nonlinear optical properties which have potential for practical laser applications.

中文翻译:

完美编码 RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) 家族中的 π 共轭阴离子,具有强二次谐波生成响应和平衡双折射

改进RE 5 (C 3 N 3 O 3 )(OH) 12 ( RE =Y, Yb, Lu)中平面π共轭六元环(C 3 N 3 O 3 ) 3-阴离子的排列系列导致强烈的二次谐波产生响应、短的 UV 截止和适度的双折射。这一发现为设计具有平衡线性和非线性光学特性的目标材料开辟了道路,这些材料具有实际激光应用的潜力。
更新日期:2022-11-07
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