当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Water-soluble Self-assembled {Pd84}Ac Polyoxopalladate Nano-wheel as a Supramolecular Host
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-11-06 , DOI: 10.1002/anie.202214203
Zoë L Sinclair 1 , Nicola L Bell 1 , Jessica R Bame 1 , De-Liang Long 1 , Leroy Cronin 1
Affiliation  

The largest anionic polyoxopalladate ({Pd84}Ac) is shown to act as a water-soluble inorganic host encapsulating organic guests in a Russian Doll fashion. NMR analysis including 1H NMR, Diffusion Ordered Spectroscopy (DOSY) and Nuclear Overhauser Spectroscopy (NOESY), as well as ESI-MS, was used to study the supramolecular chemistry of this system providing conclusive evidence that {Pd84}Ac forms a 1 : 7 host-guest complex with benzyl viologen (BV2+) in aqueous solution.

中文翻译:

水溶性自组装{Pd84}Ac Polyoxopalladate纳米轮作为超分子主体

最大的阴离子聚氧钯酸盐 ({Pd 84 } Ac ) 被证明可以作为水溶性无机宿主,以俄罗斯套娃的方式包裹有机客体。NMR 分析包括1 H NMR、扩散有序光谱 (DOSY) 和核奥弗豪瑟光谱 (NOESY) 以及 ESI-MS,用于研究该系统的超分子化学,提供 {Pd 84 } Ac 形成1确凿证据: 7 主客体复合物与苄基紫精 (BV 2+ ) 在水溶液中。
更新日期:2022-11-06
down
wechat
bug