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Correction to “Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement”
ACS Macro Letters ( IF 5.8 ) Pub Date : 2022-11-04 , DOI: 10.1021/acsmacrolett.2c00614
Hiroshi Makino , Tsuyoshi Nishikawa , Makoto Ouchi

In our recent letter “Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement” (ACS Macro Lett.2020, 9, 788–793), we miswrote the unit of y-axis in Figure 3a. The unit “eV” is incorrect, and “Hartree” is correct. This error does not affect the conclusions of the paper. The revised Figure 3 is shown. A similar error exists in the Supporting Information, so a revised version has been provided. All authors have agreed to this change. Figure 3. (a) Energy level of the SOMO on radical species corresponding to IPBpin and representative common vinyl monomers. (b, c) Spatial distribution of the SOMO on IPBpin and MMA radicals. (d, e) Spatial distribution of LUMO on IPBpin and MMA (UB3LYP/6-31G*). The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsmacrolett.2c00614. Revised version of the original SI file (PDF) Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html. This article has not yet been cited by other publications. Figure 3. (a) Energy level of the SOMO on radical species corresponding to IPBpin and representative common vinyl monomers. (b, c) Spatial distribution of the SOMO on IPBpin and MMA radicals. (d, e) Spatial distribution of LUMO on IPBpin and MMA (UB3LYP/6-31G*). The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsmacrolett.2c00614. Revised version of the original SI file (PDF) Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

中文翻译:

更正“通过自由基共聚阐明硼酸烯基酯的单体特性导致共聚物合成超出侧链置换的共聚性限制”

在我们最近的信件“Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement”(ACS Macro Lett. 2020 , 9 , 788–793)中,我们误写了y的单位- 图 3a 中的轴。单位“eV”不正确,“Hartree”是正确的。这个错误不影响论文的结论。显示了修改后的图 3。Supporting Information中也存在类似的错误,所以提供了修改后的版本。所有作者都同意这一变化。图 3. (a) SOMO 对对应于 IPBpin 和代表性常见乙烯基单体的自由基物种的能级。(b, c) SOMO 在 IPBpin 和 MMA 自由基上的空间分布。(d, e) IPBpin 和 MMA (UB3LYP/6-31G*) 上的 LUMO 空间分布。支持信息可在 https://pubs.acs.org/doi/10.1021/acsmacrolett.2c00614 免费获得。原始 SI 文件的修订版 (PDF) 大多数电子支持信息文件无需订阅 ACS 网络版即可获得。此类文件可以按文章下载以供研究使用(如果相关文章有链接的公共使用许可,则该许可可能允许其他用途)。可以通过 RightsLink 许可系统请求从 ACS 获得用于其他用途的许可:http://pubs.acs.org/page/copyright/permissions.html。这篇文章尚未被其他出版物引用。图 3. (a) SOMO 对对应于 IPBpin 和代表性常见乙烯基单体的自由基物种的能级。(b, c) SOMO 在 IPBpin 和 MMA 自由基上的空间分布。(d, e) IPBpin 和 MMA (UB3LYP/6-31G*) 上的 LUMO 空间分布。支持信息可在 https://pubs.acs.org/doi/10.1021/acsmacrolett.2c00614 免费获得。原始 SI 文件的修订版 (PDF) 大多数电子支持信息文件无需订阅 ACS 网络版即可获得。此类文件可以按文章下载以供研究使用(如果相关文章有链接的公共使用许可,则该许可可能允许其他用途)。可以通过 RightsLink 许可系统请求从 ACS 获得用于其他用途的许可:http://pubs.acs.org/page/copyright/permissions.html。
更新日期:2022-11-04
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