当前位置: X-MOL 学术J. Fluoresc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Poly(Azomethine-urethane)-based Fluorescent Chemosensor for the Detection of Cr3+ Cations in Different Water Samples
Journal of Fluorescence ( IF 2.7 ) Pub Date : 2022-10-12 , DOI: 10.1007/s10895-022-03037-7
Musa Kamaci 1
Affiliation  

A highly selective, and effective poly(azomethine-urethane)-based chemosensor (HIMA) was prepared, and it used as a fluorescent sensor for the detection of Cr3+ cations in different solutions. The HIMA was prepared in two-step reactions by using hexamethylene diisocyanate, 2,4-dihydroxy benzaldehyde, and 2-aminophenol. The sensitivity and selectivity of the fluorescent probe were tested in the presence of different metal ions. The obtained findings indicated that the chemosensor exhibited a quenching effect against the only Cr3+ ion. The limit of detection (LOD) and limit of quantitation (LOQ) of the chemosensor HIMA were calculated as 7.98 × 10–7 M, and 2.42 × 10–6 M, respectively. In addition, the binding constant (Ka) of the chemosensor was calculated as 5.31 × 105 M−1.



中文翻译:

用于检测不同水样中 Cr3+ 阳离子的基于聚(偶氮甲亚胺-氨基甲酸乙酯)的荧光化学传感器

制备了一种高选择性、高效的基于聚(偶氮甲亚胺-氨基甲酸乙酯)的化学传感器(HIMA),并将其用作检测不同溶液中Cr 3+阳离子的荧光传感器。HIMA 是通过使用六亚甲基二异氰酸酯、2,4-二羟基苯甲醛和 2-氨基苯酚通过两步反应制备的。在不同金属离子存在下测试荧光探针的灵敏度和选择性。获得的发现表明化学传感器对唯一的Cr 3+离子表现出猝灭作用。化学传感器 HIMA 的检测限 (LOD) 和定量限 (LOQ) 经计算为 7.98 × 10 –7  M 和 2.42 × 10 –6 M,分别。此外,化学传感器的结合常数 (Ka) 计算为 5.31 × 10 5  M -1

更新日期:2022-10-12
down
wechat
bug