Herein we disclose a catalytic synthesis of cycloalkanols that harnesses the potential of N₂O as an oxygen transfer agent onto sp³-hybridized carbons. The protocol is distinguished by its mild conditions and wide substrate scope, thus offering an opportunity to access carbocyclic compounds from simple precursors even in an enantioselective manner. Preliminary mechanistic studies suggest that the oxygen insertion event occurs at an alkylnickel species and that N₂O is the O transfer reagent.

中文翻译：

---

镍催化氧从 N2O 转移到 sp3 杂化碳上

_{在此，我们公开了一种利用N 2} O 作为氧转移剂到sp ³杂化碳上的潜力的环烷醇的催化合成。该协议以其温和的条件和广泛的底物范围而著称，因此即使以对映选择性的方式也可以从简单的前体中获取碳环化合物。初步机理研究表明氧插入事件发生在烷基镍物质上，N ₂ O 是 O 转移试剂。