A systematic study on taming stannaimines (R₂Sn=NR) is reported by identifying a suitable supporting ligand framework for stannylenes in combination with organic azides. The nitrogen substituent of these compounds was crucial for allowing a broad range of subsequent reactivity ranging from cycloadditions to multiple bond metathesis reactions, thus highlighting the necessary balance of rendering challenging systems isolable but still reactive.

中文翻译：

---

驯服较重的第 14 族亚胺类似物：获取锡氮 [Sn=N] 双键及其环加成/复分解化学

报道了一项关于驯服锡胺 (R ₂ Sn=NR) 的系统研究，该研究通过确定适合亚锡烯与有机叠氮化物组合的支持配体框架来进行报道。这些化合物的氮取代基对于允许从环加成到多键复分解反应的广泛后续反应性至关重要，从而突出了使具有挑战性的系统可分离但仍具有反应性的必要平衡。