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CO2 capture over steam and KOH activated biochar: Effect of relative humidity
Biomass & Bioenergy ( IF 6 ) Pub Date : 2022-09-25 , DOI: 10.1016/j.biombioe.2022.106608
Chen Zhang , Shuzhuang Sun , Shaojun Xu , Chunfei Wu

Carbon dioxide (CO2) capture is critical for emission reduction. Biochar is a promising adsorbent for CO2 capture. In this work, the effect of relative humidity and biochar activation with steam or KOH treatment on CO2 capture was investigated. The results demonstrate that the biochar sample activated by KOH has a high CO2 capture capacity (50.73 mg g−1). In addition, the biochar after 1.0 h of steam treatment showed a carbon capture capacity of 38.84 mg g−1. The results also show that the capture ability of biochar decreased as CO2 concentration decreased from 100% to 15%. The relative humidity had a negative impact on CO2 capture over biochar. The CO2 capture capability of biochar materials treated by steam decreased by a range of 31.38%–62.89% as the relative humidity rose from 8.8% to 87.9%. Furthermore, the lifetime of biochar samples at various relative humidity shows that increased relative humidity had a negative impact on CO2 adsorption due to water molecules occupying active sites.



中文翻译:

通过蒸汽和 KOH 活化的生物炭捕获 CO2:相对湿度的影响

二氧化碳 (CO 2 ) 捕获对于减排至关重要。生物炭是一种很有前途的 CO 2捕获吸附剂。在这项工作中,研究了相对湿度和使用蒸汽或 KOH 处理的生物炭活化对 CO 2捕获的影响。结果表明,KOH活化的生物炭样品具有较高的CO 2捕获能力(50.73 mg g -1)。此外,蒸汽处理 1.0 h 后的生物炭显示出 38.84 mg g -1的碳捕获能力。结果还表明,随着CO 2浓度从100%下降到15%,生物炭的捕获能力下降。相对湿度对CO 2有负面影响捕获 biochar。随着相对湿度从8.8%上升到87.9%,蒸汽处理的生物炭材料的CO 2捕集能力下降了31.38%~62.89%。此外,生物炭样品在各种相对湿度下的寿命表明,由于水分子占据活性位点,增加的相对湿度对 CO 2吸附具有负面影响。

更新日期:2022-09-25
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