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The Kauzmann Transition to an Ideal Glass Phase
arXiv - PHYS - Disordered Systems and Neural Networks Pub Date : 2022-09-22 , DOI: arxiv-2209.11049 Chiara Cammarota, Misaki Ozawa, Gilles Tarjus
arXiv - PHYS - Disordered Systems and Neural Networks Pub Date : 2022-09-22 , DOI: arxiv-2209.11049 Chiara Cammarota, Misaki Ozawa, Gilles Tarjus
The idea that a thermodynamic glass transition of some sort underlies the
observed glass formation has been highly debated since Kauzmann first stressed
the hypothetical entropy crisis that could take place if one were able to
equilibrate supercooled liquids below the experimental glass transition
temperature $T_g$. This a priori unreachable transition at some $T_K
中文翻译：
考兹曼过渡到理想玻璃相
自从考兹曼第一次强调如果能够平衡低于实验玻璃化转变温度 $T_g$ 的过冷液体可能发生的假设熵危机，关于某种热力学玻璃化转变是观察到的玻璃形成的基础的想法一直备受争议。这是在某个 $T_K 处的先验不可达转换
更新日期：2022-09-23
中文翻译：
考兹曼过渡到理想玻璃相
自从考兹曼第一次强调如果能够平衡低于实验玻璃化转变温度 $T_g$ 的过冷液体可能发生的假设熵危机，关于某种热力学玻璃化转变是观察到的玻璃形成的基础的想法一直备受争议。这是在某个 $T_K 处的先验不可达转换
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