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Hierarchically designed NiCo2O4 nanowire/NiCo2O4 nanosheet electrodes for high-performance energy storage applications
Surfaces and Interfaces ( IF 6.2 ) Pub Date : 2022-09-15 , DOI: 10.1016/j.surfin.2022.102340
A.A. Yadav , Y.M. Hunge , Bo-Kyong Kim , Seok-Won Kang

A NiCo2O4 nanowire/NiCo2O4 nanosheet composite with a nanostructure was fabricated on nickel foam for use in high-performance supercapacitors by using two-step solution-based approaches such as hydrothermal and chemical bath deposition methods. In this study, the supercapacitive performance of NiCo2O4 nanowires was compared with that of NiCo2O4 nanowire/NiCo2O4 nanosheet arrays in a 2 M KOH electrolyte. The electrochemical study shows that NiCo2O4 nanowires/NiCo2O4 nanosheets exhibit higher electrochemical performance than NiCo2O4 nanowires. The NiCo2O4 nanowires/NiCo2O4 nanosheets (1866 F/g) have a high specific capacitance than NiCo2O4 nanowires (1023 F/g), at 2 A/g. Further, NiCo2O4 nanowire/NiCo2O4 nanosheet arrays show high electrochemical cycling stability of 94.8% over 5,000 cycles. This enhanced electrochemical performance is attributed to the hierarchically arranged morphology of the NiCo2O4 nanowire/NiCo2O4 nanosheet composite, which provides a large number of active sites for redox reactions, and fast ion-transfer ability.



中文翻译:

用于高性能储能应用的分层设计的 NiCo2O4 纳米线/NiCo2O4 纳米片电极

通过使用两步溶液法(如水热法和化学浴沉积法),在泡沫镍上制造了具有纳米结构的 NiCo 2 O 4纳米线/NiCo 2 O 4纳米片复合材料,用于高性能超级电容器。在本研究中,将 NiCo 2 O 4 纳米线的超级电容性能与 NiCo 2 O 4 纳米线/NiCo 2 O 4纳米阵列2 M KOH电解液的超级电容性能进行了比较。电化学研究表明NiCo 2 O 4纳米线/NiCo 2 O 4纳米片表现出比NiCo 2 O 4纳米线更高的电化学性能。NiCo 2 O 4纳米线/NiCo 2 O 4纳米片(1866 F/g)具有比NiCo 2 O 4纳米线(1023 F/g)高的比电容,为2 A/g。此外,NiCo 2 O 4纳米线/NiCo 2 O 4纳米片阵列在5,000次循环中表现出94.8%的高电化学循环稳定性。这种增强的电化学性能归因于 NiCo 2 O 4纳米线/NiCo 2的分层排列形态O 4纳米片复合材料,为氧化还原反应提供了大量的活性位点,并具有快速的离子转移能力。

更新日期:2022-09-15
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