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Self-Healing and Shape Memory Hypercrosslinked Metal-Organic Polyhedra Polymers via Coordination Post-Assembly
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-09-09 , DOI: 10.1002/anie.202212253
Jinjin Liu 1 , Jiamin Li 1 , Shan Qiao 2 , Zhifang Wang 1 , Penghui Zhang 1 , Xiangqian Fan 3 , Peng Cheng 1, 4 , Yue-Sheng Li 5 , Yao Chen 1, 2 , Zhenjie Zhang 1, 2, 4
Affiliation  

A type of coordination hypercrosslinked MOP (CHMOP) polymers was prepared using soluble and well-defined MOPs as high-connectivity building blocks. The introduction of MOPs constructs a coordination dynamic network that not only enhances mechanical properties but also realizes multifunctionality including self-healing, shape memory, solution processability, and 3D printing. CHMOPs provide a novel platform for expansion of the smart soft materials.

中文翻译:

自修复和形状记忆超交联金属有机多面体聚合物通过配位后组装

使用可溶性和定义明确的MOPs作为高连接性构建块制备了一种配位超交联MOP(CHMOP)聚合物。MOPs的引入构建了一个协调动态网络,不仅增强了机械性能,而且实现了包括自愈、形状记忆、溶液加工性和3D打印在内的多功能。CHMOPs 为智能软材料的扩展提供了一个新颖的平台。
更新日期:2022-09-09
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